97580-26-2

Upstream product

• 97580-22-8 ethyl 2-(1-4'-methoxyphenylethenyl)-5-hexenoate 
• 7706-82-3 (E)-ethyl 3-(4-methoxyphenyl)but-2-enoate 

Downstream Products

• 109988-59-2 N-<2-(1-4'-methoxyphenylethenyl)-5-hexenyl>oxazolidine-2,4-dione 
• 97579-67-4 (4aS,6R,8aR)-6-Formyloxy-4a-(4-methoxy-phenyl)-octahydro-isoquinoline-2-carboxylic acid methyl ester 
• 97579-75-4 Formic acid 4-(methoxycarbonylamino-methyl)-3-(4-methoxy-phenyl)-3-methyl-cyclohexyl ester 
• 97579-71-0 (4aS,6R,8aR)-4a-(4-Methoxy-phenyl)-2-methyl-decahydro-isoquinolin-6-ol 
• 99809-86-6 (4aR,6S,8aS)-4a-(4-Methoxy-phenyl)-octahydro-isoquinoline-2,6-dicarboxylic acid 2-methyl ester 
• 99809-89-9 (4aS,6S,8aS)-4a-(4-Methoxy-phenyl)-2-methyl-decahydro-isoquinolin-6-ol 
• 97580-38-6 Hydroxymethyl-{2-[1-(4-methoxy-phenyl)-vinyl]-hex-5-enyl}-carbamic acid methyl ester 
• 97580-35-3 {2-[1-(4-Methoxy-phenyl)-vinyl]-hex-5-enyl}-carbamic acid methyl ester 
• 109988-63-8 N-<2-(1-4'-methoxyphenylethenyl)-5-hexenyl>-4-phenylthiooxazolidin-2-one 
• 97580-30-8 2-{2-[1-(4-Methoxy-phenyl)-vinyl]-hex-5-enyl}-isoindole-1,3-dione 

Relevant academic research and scientific papers

A Highly Diastereoselective Synthesis of cis-4a-Aryloctahydro-cyclopentapyridine Derivatives through Tandem Radical Cyclization of α-amino Radical Polyene Species

8a-Aryloxazolocyclopentapyridines (9a-c) were prepared via a route involving radical cyclization of α-acylamino radical polyene species generated by treatment of 4-phenylthiooxazolidin-2-ones (8a-c) with tri-n-butyltin hydride in the presence of azobisisobutyronitrile (AIBN).Conversion of 9a to cis-octahydro-2,5-dimethyl-4a-phenylcyclopentapyridine (19) was successfully achieved via a route involving ring cleavage of the oxazolidinone ring of 9a, oxidation of hydroxymethyl group, and decarbonylation.Keywords - radical cyclization; cyclopentapyridine; α-acylamino radical; α-amino radical-polyene; tandem radical cyclization; decarbonylation

AN EFFICIENT DIASTEREOSELECTIVE SYNTHESIS OF 6-HYDROXY-4a--trans-DECAHYDROISOQUINOLINE

A high diastereoselective synthesis of 6-hydroxy-4a-aryl-trans-decahydroisoquinoline derivatives was achieved by an application of N-acyliminium ion-induced polyene cyclization procedure.