97607-84-6Relevant academic research and scientific papers
Generation of acyloxyketenes from unstable mesoionic 1,3-dioxolium-4-olates and their reaction with ketenophiles to give [2 + 2] cycloadducts
Hamaguchi, Masashi,Tomida, Naoki,Iyama, Yuji,Oshima, Takumi
, p. 5162 - 5170 (2007/10/03)
Fast ring opening of mesoionic 1,3-dioxolium-4-olates, generated by Rh 2(OAc)4-catalyzed decomposition of phenyldiazoacetic anhydride derivatives, to acyloxyphenylketenes was demonstrated by trapping the ketenes with several ketenoph
Formation and Reactions of Mesoionic Anhydro-4-hydroxy-1,3-dioxolium Hydroxides
Hamaguchi, Masashi,Nagai, Toshikazu
, p. 190 - 191 (2007/10/02)
A novel mesoionic system, anhydro-4-hydroxy-1,3-dioxolium hydroxide, was formed by intramolecular carbene-carbonyl reaction on catalytic decomposition of α-diazoacetic benzoic anhydrides and trapped with acetylenic compounds to give furan derivatives as f
