97634-53-2

Basic information

• Product Name: (E,E)-3,7-dimethyl-9-(phenylthio)nona-3,7-dienal
• CAS NO: 97634-53-2
• Molecular Weight: 274.427
• Mol File: 97634-53-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E,E)-3,7-dimethyl-9-(phenylthio)nona-3,7-dienal(CAS DataBase Reference)
• NIST Chemistry Reference: (E,E)-3,7-dimethyl-9-(phenylthio)nona-3,7-dienal(97634-53-2)
• EPA Substance Registry System: (E,E)-3,7-dimethyl-9-(phenylthio)nona-3,7-dienal(97634-53-2)

Safety Data

• Hazardous Substances Data: 97634-53-2(Hazardous Substances Data)

Upstream product

• 97634-70-3 Toluene-4-sulfonic acid (2E,6E)-3,7-dimethyl-nona-2,6,8-trienyl ester 
• 97634-58-7 (E,E)-3,7-dimethyl-1-(phenylthio)nona-2,6,8-triene 
• 97634-57-6 (E,E)-3,7-dimethylnona-2,6,8-trien-1-ol 
• 97634-69-0 (E,E)-3,7-dimethyl-2,6,8-nonatrien-1-ol acetate 
• 37905-02-5 (2E,6E)-3,7-dimethyl-8-oxoocta-2,6-dien-1-yl acetate 
• 37905-03-6 8-hydroxygeranyl acetate 
• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 97634-59-8 (E,E)-3,7-dimethyl-9-(phenylthio)nona-3,7-dienol 

Downstream Products

• 97634-71-4 Toluene-4-sulfonic acid (E)-4-[(4R,5R)-4-((2E,6E)-2,6-dimethyl-8-phenylsulfanyl-octa-2,6-dienyl)-2,2-dimethyl-[1,3]dioxan-5-yl]-2-methyl-but-2-enyl ester 
• 97634-62-3 erythro-9,15-O-isopropylidene-9,14-dihydroxy-10-(hydroxymethyl)-1-(phenylthio)-3,7,13-trimethyltetradeca(E,E,E)-2,6,12-triene 
• 97644-31-0 (4S,5S)-5-((E)-4-Chloro-3-methyl-but-2-enyl)-4-((2E,6E)-2,6-dimethyl-8-phenylsulfanyl-octa-2,6-dienyl)-2,2-dimethyl-[1,3]dioxane 
• 97634-60-1 erythro-9,14-dihydroxy-10-(1,2-dihydroxy-2-methylpropyl)-1-(phenylthio)-3,7,13-trimethyltetradeca-(E,E,E)-2,6,12-triene 
• 97634-61-2 erythro-9,14-dihydroxy-10-(hydroxymethyl)-1-(phenylthio)-3,7,13-trimethyltetradeca-(E,E,E)-2,6,12-triene 
• 97634-72-5 (5E,9E)-(2S,3R)-3-Hydroxy-2-((E)-4-hydroxy-3-methyl-but-2-enyl)-5,9-dimethyl-11-phenylsulfanyl-undeca-5,9-dienal 
• 97644-30-9 erythro-9-hydroxy-10-<1-oxo-2-methyl-2-(trimethylsiloxy)propyl>-1-(phenylthio)-14-(trimethylsiloxy)-3,7,13-trimethyltetradeca-(E,E,E)-2,6,12-triene 

Relevant articles and documents

Synthetic Studies Directed toward Cembranolides. Synthesis of the Basic Nucleus of Crassin Acetate

A stereospecific synthesis of the basic crassin acetate nucleus, erythro-1-(hydroxymethyl)-14-hydroxy-4,8,12-trimethylcyclotetradeca-(E,E,E)-3,7,11-triene, has been achieved.Stereospecific syntheses of the two precursors to this ring system, (E,E)-3,7-dimethyl-9-(phenylthio)nona-3,7-dienal and (E)-2,8-bis(trimethylsiloxy)-2,7-dimethyloct-6-en-3-one, have been developed.These moieties were combined via an aldol condensation to yield erythro-9-hydroxy-10--1-(phenylthio)-14-(trimethylsiloxy)-3,7,13-trimethyltetradeca-(E,E,E)-2,6,12-triene which, in a series of reactions, was cyclized to the titled 14-membered ring system.