97752-14-2

Upstream product

• 107-30-2 chloromethyl methyl ether 
• 132048-19-2 [(Z)-1-((E)-5-Benzyloxy-pent-1-enyl)-7,7-dimethoxy-3-methoxymethoxy-hept-1-enyl]-trimethyl-silane 
• 132048-18-1 (8E,6Z)-1,1-dimethoxy-5-(methoxymethoxy)-7-(trimethylsilyl)undeca-6,8-dien-12-ol 
• 132048-16-9 <(E)-7,7-dimethoxy-1-iodo-3-(methoxymethoxy)hept-1-enyl>trimethylsilane 
• 132048-15-8 <7,7-dimethoxy-3-(methoxymethoxy)hept-1-ynyl>trimethylsilane 
• 132048-14-7 (7,7-dimethoxy-3-hydroxyhept-1-ynyl)trimethylsilane 
• 54655-07-1 lithium trimethylsilylacetylenide 
• 50789-30-5 5,5-dimethoxypentanal 
• 1071074-09-3 (2Z,4E)-8-Benzyloxy-3-trimethylsilanyl-octa-2,4-dienal 
• 76711-46-1 Trimethyl-[(E)-3-(tetrahydro-pyran-2-yloxy)-propenyl]-silane 
• 36551-06-1 3-(tetrahydropyran-2-yloxy)-1-trimethylsilylprop-1-yne 
• 132048-20-5 (6Z,8E)-12-Benzyloxy-5-methoxymethoxy-7-trimethylsilanyl-dodeca-6,8-dienal 
• 2605-68-7 methyl 2-(triphenylphosphoranylidene)propionate 

Downstream Products

• 132048-22-7 (1R,2R,4aS,5R,8aR)-2-(3-Benzyloxy-propyl)-5-methoxymethoxy-1-methyl-4-trimethylsilanyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid methyl ester 
• 132048-22-7 methyl 6β-<3-(benzyloxy)prop-1-yl>-1α-(methoxymethoxy)-5α-methyl-8-(trimethylsilyl)-1,2,3,4,4aβ.5.6.7aα-octahydroanphthalene-5β-carboxylate 
• 132048-22-7 (1R,2S,4aR,5R,8aR)-2-(3-Benzyloxy-propyl)-5-methoxymethoxy-1-methyl-4-trimethylsilanyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid methyl ester 

Relevant academic research and scientific papers

Enantioselective Synthesis of the Bottom Half of Chlorothricolide. 3. Studies of the Steric Directing Group Strategy for Stereocontrol in Intramolecular Diels-Alder Reactions

The intramolecular Diels-Alder reactions of a series of C(7)-alkoxy-substituted 2(E),8(Z),10(E)-undecatrienoates and trienals containing removable C(9)-Br or C(9)-SiMe3 substituents (11, 12, 13, 33, 42, 43, 44, 45) were studied as part of a programm direc

Stereocontrol in the Intramolecular Diels-Alder Reaction. 7. Use of the Trimethylsilyl Group as a Removable Stereocontrol Element to Provide Greatly Enhanced Levels of Diastereoselection

Introduction of the trimethylsilyl group at defined locations in triene substrates which undergo closure by intramolecular Diels-Alder cycloaddition to both hydrindene and octalin systems results in greatly enhanced levels of diastereoselection