132048-22-7Relevant academic research and scientific papers
Enantioselective Synthesis of the Bottom Half of Chlorothricolide. 3. Studies of the Steric Directing Group Strategy for Stereocontrol in Intramolecular Diels-Alder Reactions
Roush, William R.,Kageyama, Masanori,Riva, Renata,Brown, Bradley B.,Warmus, Joseph S.,Moriarty, Kevin J.
, p. 1192 - 1210 (2007/10/02)
The intramolecular Diels-Alder reactions of a series of C(7)-alkoxy-substituted 2(E),8(Z),10(E)-undecatrienoates and trienals containing removable C(9)-Br or C(9)-SiMe3 substituents (11, 12, 13, 33, 42, 43, 44, 45) were studied as part of a programm direc
Stereocontrol in the Intramolecular Diels-Alder Reaction. 7. Use of the Trimethylsilyl Group as a Removable Stereocontrol Element to Provide Greatly Enhanced Levels of Diastereoselection
Boeckman, Robert K.,Barta, Thomas E.
, p. 3421 - 3423 (2007/10/02)
Introduction of the trimethylsilyl group at defined locations in triene substrates which undergo closure by intramolecular Diels-Alder cycloaddition to both hydrindene and octalin systems results in greatly enhanced levels of diastereoselection
