97781-07-2Relevant articles and documents
Synthesis of unsymmetrically substituted benzils via the Friedel-Crafts reaction of arenes with α-chloro-α-(methylthio)acetophenones
Ishibashi,Matsuoka,Ikeda
, p. 1854 - 1856 (2007/10/02)
Lewis acid-promoted reactions of arenes with α-chloro-α-(methylthio)acetophenones gave the Friedel-Crafts reaction products, which were then treated with 3 molar eq of cupric chloride in aqueous acetone to afford the unsymmetrically substituted benzils.
MILD REACTION OF PUMMERER REARRANGEMENT PRODUCTS WITH AROMATIC COMPOUNDS IN THE PRESENCE OF LEWIS ACIDS. APPLICATION TO THE PREPARATION OF ARYLMETHYLENE KETONES, ARYLACETOESTERS, AND ARYLACETONITRILES.
Stamos, Ioannis K.
, p. 477 - 480 (2007/10/02)
Pummerer intermediates generated from precursors (3), (4) and (5) reacted mildly with aromatic compounds in the presence of Lewis acids to give the corresponding sulfides which in turn desulfurized to arylmethylene ketones, arylacetoesters, and arylaceton