97817-99-7

Basic information

• Product Name: allyl 2,3-di-Ο-benzyl-β-D-galactopyranoside
• Synonyms: allyl 2,3-di-Ο-benzyl-β-D-galactopyranoside
• CAS NO: 97817-99-7
• Molecular Weight: 400.472
• Mol File: 97817-99-7.mol

Chemical Properties

• CAS DataBase Reference: allyl 2,3-di-Ο-benzyl-β-D-galactopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: allyl 2,3-di-Ο-benzyl-β-D-galactopyranoside(97817-99-7)
• EPA Substance Registry System: allyl 2,3-di-Ο-benzyl-β-D-galactopyranoside(97817-99-7)

Safety Data

• Hazardous Substances Data: 97817-99-7(Hazardous Substances Data)

Upstream product

• 71925-96-7 allyl-2,3-di-O-benzyl-4,6-O-benzylidene-β-D-galactopyranoside 
• 117780-16-2 allyl 2,3-di-O-benzyl-4-O-chloroacetyl-β-D-galactopyranoside 
• 100-39-0 benzyl bromide 
• 2595-07-5 allyl D-galactopyranoside 
• 10343-15-4 allyl 2,3,4,6-tetra-O-acetyl-D-galactopyranoside 
• 4163-60-4 β-D-galactose peracetate 
• 71925-95-6 allyl 4,6-O-benzylidene-β-D-galactopyranoside 
• 10343-15-4 allyl-2,3,4,6-tetra-O-acetyl-β-D-galactopyranoside 
• 92516-88-6 allyl 4,6-O-isopropylidene-β-D-galactopyranoside 
• 117780-15-1 allyl 2,3-di-O-benzyl-4,6-O-isopropylidene-β-D-galactopyranoside 

Downstream Products

• 311797-10-1 benzyl (allyl 2,3-di-O-benzyl-β-D-galactopyranoside)uronate 
• 1448429-69-3 benzyl (2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl)-(1→4)-(allyl 2,3-di-O-benzyl-β-D-galactopyroside)uronate 
• 1448429-74-0 benzyl (3,4-di-O-benzyl-2-O-levulinoyl-α-L-rhamnopyranosyl)-(1→4)-(allyl 2,3-di-O-benzyl-β-D-galactopyranoside)uronate 
• 1448429-75-1 benzyl (3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1→4)-(allyl 2,3-di-O-benzyl-β-D-galactopyranoside)uronate 
• 113765-34-7 C₇₆H₈₄O₁₉ 
• 113765-27-8 Chloro-acetic acid (2R,3S,4S,5R,6R)-2-acetoxymethyl-6-((2R,3S,4S,5R,6R)-2-acetoxymethyl-6-allyloxy-4,5-bis-benzyloxy-tetrahydro-pyran-3-yloxy)-4,5-bis-benzyloxy-tetrahydro-pyran-3-yl ester 
• 97818-02-5 allyl-6-O-allyl-2,3-di-O-benzyl-4-O-methyl-β-D-galactopyranoside 
• 97818-03-6 allyl-2,3-di-O-benzyl-4-O-methyl-β-D-galactopyranoside 
• 97818-04-7 2,3-di-O-benzyl-4-O-methyl-α/β-D-galactopyranose 
• 97818-05-8 2,3-di-O-benzyl-4-O-methyl-D-galactitol 
• 117300-01-3 3,4-di-O-benzyl-2-O-methyl-L-lyxopyranose 
• 117780-14-0 methyl (2,3-di-O-benzyl-4-O-chloroacetyl-α-D-galactopyranosyl fluoride)uronate 
• 117780-28-6 methyl (2,3-di-O-benzyl-4-O-chloroacetyl-β-D-galactopyranosyl fluoride)uronate 
• 93338-32-0 methyl 2,3-di-O-benzyl-4-O-chloroacetyl-α-D-galactopyranuronate 

Relevant articles and documents

Structural Studies of the O-Acetyl-Containing O-Antigen from a Shigella flexneri Serotype 6 Strain and Synthesis of Oligosaccharide Fragments Thereof

Extensive analysis by NMR spectroscopy of the delipidated lipopolysaccharide of Shigella flexneri serotype 6 strain MDC 2924-71 confirmed the most recently reported structure of the O-antigen repeating unit as {→4)-β-D-GalpA-(1→3)-β-D-GalpNAc-(1→2) -α-L-R

Synthesis of oligosaccharide fragments of the rhamnogalacturonan of Nerium indicum

Three trisaccharides, one pentasaccharide, and one heptasaccharide, namely α-D-GalA-(1→2)-α-L-Rha-(1→4)-β-D-GalA-OC 3H7 (1), α-L-Rha-(1→4)-α-D-GalA- (1→4)-β-D-GalA-OC3H7 (2), α-D-GalA- (1→4)-α-DGalA-(1→2)-α-L-Rh

Synthesis of allyl 3-deoxy- and 4-deoxy-β-D-galactopyranoside and simultaneous preparations of Gal(1 → 2)- and Gal(1 → 3)-linked disaccharide glycosides

Syntheses of galactose derivatives that are useful in probing the binding specificity of galactose-specific lectins are reported. These include allyl 3-deoxy- and 4-deoxy-β-D-xylo-hexopyranoside and several disaccharide glycosides having Gal(1 → 2) and Gal(1 → 3) linkages. The β-linked Gal disaccharide isomers were produced using 2,3,4,6-tetra-O-acetyl-α-D- galactopyranosyl bromide as glycosyl donor and the 4,6-O-benzylidene derivatives of allyl β-D-galactopyranoside, α-D-glucopyranoside, α-D- mannopyranoside, and 2-acetamido-2-deoxy-α-D-galactopyranoside as acceptors. Only the Gal(1 → 3)-linked disaccharide was obtained when the benzylidene derivatives of the mannopyranoside and 2-acetamido-2-deoxygalactopyranoside were used. Attempts at the preparation of Gal(α, 1 → 2)Gal and Gal(α, 1 → 3)Gal disaccharide glycosides were made using the same strategy, but employing the 1-trichloro-acetimidate or 1-N-methylacetimidate of 2,3,4,6- tetra-O-benzyl-D-galactopyranose as the glycosyl donor. The latter imidate produced a mixture of Gal(α, 1 → 2)Gal and Gal(α, 1 → 3)Gal derivatives as major products, but the former gave the Gal(β, 1 → 2)Gal isomer as the major product. Syntheses of galactose derivatives that are useful in probing the binding specificity of galactose-specific lectins are reported. These include allyl 3-deoxy- and 4-deoxy-β-D-xylo-hexophyranoside and several disaccharide glycosides having Gal(a→2)Gal and Gal(1→3) linkages. The β-linked Gal disaccharide isomers were produced using 2,3,4,6-tetra-O- acetyl-α-D-galactopyronosyl bromide as glycosyl donor and the 4,6-O-benzylidene deriatives of allyl β-D-galactopyranoside, α-D-glucopyranoside, α-D-manopyranoside, and 2-acetamido-2-deoxy-α-D-galactopyranoside as acceptors. Only the Gal(2→3)-linked disaccharide was obtained when the benzylidene derivatives of the mannopyranosde and 2-acetamido-2-deoxygalactopyranoside were used. Attempts at the preparation of Gal(α, 1→2)Gal and Gal(α, 1→3)Gal disaccharide glycosides were made using the same strategy, but employing the 1-trichloroacetimidate or 1-N-methylacetimidate of 2,3,4,6-tetra-O-benzyl-D-galactopyranose as the glycosyl donor. The latter imidate produced a mixture of Gal(α, 1→2)Gal and Gal(α, 1→3)Gal derivatives as major products, but the former gave the Gal(β, 1→2)Gal isomer as the major product.