97826-85-2

Upstream product

• 636-98-6 p-nitrobenzene iodide 
• 111-34-2 -butyl vinyl ether 
• 591-50-4 iodobenzene 
• 112087-62-4 1-phenyl-1,4-hexadien-3-ol 
• 122-04-3 4-nitro-benzoyl chloride 
• 62-23-7 4-nitro-benzoic acid 
• 586-78-7 para-nitrophenyl bromide 
• 17763-80-3 para-nitrophenyl triflate 

Relevant academic research and scientific papers

Regiochemistry of Palladium-Catalyzed Arylation Reactions of Enol Ethers. Electronic Control of Selection for α- or β-Arylation

The regiochemistry of palladium-mediated arylation Heck arylation) of enol ethers is sensitive to (a) the structure of the enol ether, (b) the arylating agent used, and (c) the reaction medium-catalyst system.By control of these parameters a 50-fold varia

α-Regioselectivity in Palladium-Catalyzed Arylation of Acyclic Enol Ethers

Regioselective α-arylation of acyclic enol ethers by aryl trifluoromethanesulfonates, aryl bromide, aryl iodides, and aroyl chlorides is described.The outcome of the reaction proved to be dependent from the relationship between ligand and counterion in the oxidative complex.

Synthesis of β-Arylvinyl Ethers by the Palladium-Catalyzed Reaction of Aroyl Chlorides with Vinyl Ethers

Reaction of aroyl chlorides with butyl vinyl ether in the presence of a palladium catalyst and an amine base affords β-arylvinyl ethers in 40-60percent yield.Both with regard to regioselectivity and reaction rate, aroyl chlorides were superior to aryl bro