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Low Temperature Free-Radical Reactions Initiated with tert-Butyl p-Benzoylperbenzoate. Selective Acyl Radical Additions to Substituted Olefins
Gottschalk, Peter,Neckers, D. C.
, p. 3498 - 3502 (1985)
Competition experiments involving acyl radical additions to simple and electron-deficient olefins showed a definite preference for acylation of the latter olefin.This selectivity was significantly enhanced by using low temperature initiation with tert-butyl p-benzoylperbenzoate (1), which allows selective initiation of free-radical cyclization reactions that have synthetic importance.
