97839-36-6

Basic information

• Product Name: Benzenecarbothioic acid, 3-chloro-, S-phenyl ester
• CAS NO: 97839-36-6
• Molecular Formula: C13H9ClOS
• Molecular Weight: 248.733
• Mol File: 97839-36-6.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzenecarbothioic acid, 3-chloro-, S-phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarbothioic acid, 3-chloro-, S-phenyl ester(97839-36-6)
• EPA Substance Registry System: Benzenecarbothioic acid, 3-chloro-, S-phenyl ester(97839-36-6)

Safety Data

• Hazardous Substances Data: 97839-36-6(Hazardous Substances Data)

Upstream product

• 930-69-8 sodium thiophenolate 
• 618-46-2 m-Chlorobenzoyl chloride 
• 108-98-5 thiophenol 
• 882-33-7 diphenyldisulfane 
• 625-99-0 3-iodochlorobenzene 
• 82102-37-2 9-methyl-9H-fluorene-9-carbonyl chloride 
• 587-04-2 m-Chlorobenzaldehyde 
• 201230-82-2 carbon monoxide 
• 535-80-8 3-chlorobenzoate 

Downstream Products

• 62482-45-5 1-(m-chlorophenyl)-2-phenylethanone 
• 38700-88-8 m-chlorophenyl phenylsulfide 
• 90982-74-4 phenyl m-chlorobenzenedithiocarboxylate 
• 873-63-2 m-chlorobenzyl alcohol 

Relevant articles and documents

Rh(I)-Catalyzed Intramolecular Decarbonylation of Thioesters

Decarbonylative synthesis of thioethers from thioesters proceeds in the presence of a catalytic amount of [Rh(cod)Cl]2 (2 mol %). The protocol represents the first Rh-catalyzed decarbonylative thioetherification of thioesters to yield valuable thioethers. Notable features include the absence of phosphine ligands, inorganic bases, and other additives and excellent group tolerance to aryl chlorides and bromides that are problematic using other metals to promote decarbonylation. Gram scale synthesis, late-stage pharmaceutical derivatization, and orthogonal site-selective cross-couplings by C-S/C-Br cleavage are reported.

Syntheses of thiol and selenol esters by oxidative coupling reaction of aldehydes with RYYR (Y = S, Se) under metal-free conditions

Thiol and selenol esters were synthesized by a direct oxidative coupling reaction of aldehydes with disulfides or diselenides in ethyl acetate under metal-free conditions. Among the oxidants examined, tert-butyl peroxide (TBP) was shown to give the best results. For the substrates with both electron-donating and electron-withdrawing substituents, the reaction proceeded smoothly and gave moderate to good yields. Compared with the previous method, the present route is very simple, atom-economical and environmentally friendly. This journal is the Partner Organisations 2014.

Tetraethylammonium bromide-catalyzed oxidative thioesterification of aldehydes and alcohols

A metal-free, tetraethylammonium bromide-catalyzed oxidative coupling of aldehydes or alcohols with thiophenols or disulfides has been developed. This protocol affords an efficient and inexpensive approach to the synthesis of a wide range of thioesters in high yields. Copyright