97847-64-8

Upstream product

• 32399-48-7 cycloheptatriene-7-carbonyl chloride 
• 591-51-5 phenyllithium 
• 97847-91-1 2,4,6-Cycloheptatrien-1-ylphenyl(trimethylsiloxy)acetonitril 
• 25438-37-3 phenyl(trimethylsiloxy)acetonitrile 
• 62485-97-6 phenylmanganese iodide 
• 64596-37-8 Methylmanganiodid 

Downstream Products

• 107167-38-4 Toluene-4-sulfonic acid cyclohepta-2,4,6-trienylidene-phenyl-methyl ester 
• 104876-72-4 anti-3-Benzoyl-N-methyl-6,7-diaza-exo-tricyclo<3.2.2.0^2,4>non-8-en-6,7-dicarboximid 

Relevant academic research and scientific papers

PREPARATION OF SOME 2,4,6-CYCLOHEPTATRIENE-1-YL KETONES. STRONG PREFERENCE FOR THE NORCARADIENE ISOMER IN THE CASE OF THE 2,4,6-CYCLOHEPTATRIENE-1-YL t-BUTYL KETONE

t-Butyl, i-propyl and phenyl 2,4,6-cycloheptatriene-1-yl ketone (1a,c,d, respectively) have been synthesized.At -139 deg C, rather unexpectedly, the t-butyl ketone 1a exists in a 1:1 equilibrium with its norcaradiene isomer 2a.

Syntheses of 2,4,6-Cycloheptatrien-1-yl Ketones

The phenyl(trimethylsiloxy)acetonitriles 5a - g, prepared by umpolung reactions with trimethylsiloxy cyanide, reacted after deprotonation with the tropylium cation 6 to give the 2,4,6-cycloheptatrien-1-ylaryl(trimethylsiloxy)acetonitriles 7a - g.After cle

FACILE SYNTHESES OF 2,4,6-CYCLOHEPTATRIENYL KETONES

The synthesis of the 2,4,6-cycloheptatrienyl ketones 1a-1e by two alternative routes is reported: Route 1): The adducts 3a-c from the phenyl(trimethylsiloxy)-acetonitriles 2a-c, known as "umpolung" reagents, and tropylium tetrafluoroborate are cleaved by