97848-36-7Relevant academic research and scientific papers
A CONVENIENT SYNTHESIS OF SYMMETRICAL DIARYL TELLURIDES USING TELLURIUM/RONGALITE AS TELLURATION SYSTEM
Suzuki, Hitomi,Inouye, Masahiko
, p. 389 - 390 (1985)
Sodium telluride, prepared by reducing tellurium with rongalite in dilute aqueous sodium hydroxide, readily reacts with nonactivated aryl iodides to afford symmetrical diaryl tellurides in good yields.
Carbon-carbon bond forming reactions via Pd-catalyzed detellurative homocoupling of diorganyl tellurides
Zhang, Shaozhong,Kolluru, Lalitha,Vedula, Souseelya K.,Whippie, Drew,Jin, Jin
supporting information, p. 3594 - 3597 (2017/08/23)
A simple and highly efficient method for the constructions of Csp-Csp, Csp2-Csp2 and Csp3-Csp3 bonds is reported. The symmetrical diaryl tellurides undergo detellurative homocouplings to afford symmetrical biaryl products. The reactions are carried out at ambient temperature using PdCl2 as a catalyst in the presence of Ag2O and Na2CO3. Similarly, the detellurative homocouplings of dibenzyl telluride and bis(phenylethynyl)telluride give bibenzyl and the conjugated diyne, respectively.
