97915-27-0Relevant academic research and scientific papers
Functional trifluorovinyl monomers and their copolymerization with fluoroolefins
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Page 9, (2010/02/08)
Functional trifluorovinyl monomers and their copolymerization with fluoroolefins Functional trifluorovinyl monomers, process for the copolymerization of trifluorovinyl monomers with fluoroolefins and use of these trifluorovinyl monomers in forming fluoroelastomers. Copolymers resulting from this copolymerization process and process for crosslinking these copolymers.
The addition of F113 and CFCl2CF2CFCl2 to alkenes promoted by sodium dithionite
Wu, Fan-Hong,Huang, Wei-Yuan
, p. 85 - 87 (2007/10/03)
The addition of F113 and CFCl2CF2CFCl2 to alkenes promoted by sodium dithionite occurs to give the corresponding fluoroalkylation products in moderate yields.
Synthesis and polymerization of fluorinated monomers bearing a reactive lateral group. : Part 3 - synthesis of trifluorovinyl hydroxy and acetoxy monomers
Ameduri,Boutevin,K. Kostov,Petrova
, p. 69 - 76 (2007/10/03)
The preparation of two functional perfluorovinyl monomers useful as comonomers in the copolymerization of commercially available monomers is presented. First, 1-iodo-1,2-dichloro-1,2,2-trifluoro ethane (1) was added to allyl alcohol under several initiating conditions and it was found that AIBN is the best initiator. Then, the selective reduction of the iodine atom in the presence of tributyl stannane gave ClCF2CFClC3H6OH quantitatively and its dechlorination was optimized leading to F2C=CFC3H6OH in 50% overall yield from (1). This monomer was quantitatively acetylated by acetyl chloride. All these products and intermediates were characterized by 1H, 19F and 13C-NMR spectroscopy, and simulated spectra were in very good agreement with those observed experimentally.
