97937-27-4Relevant academic research and scientific papers
Synthesis of linearly fused tricyclic compounds via thermal oxy-Cope rearrangement
Shanmugam, Ponnusamy,Rajagopalan, Krishnamoorthy
, p. 7737 - 7744 (2007/10/03)
Linearly fused tricyclic [5.6.5] and [6.6.6] compounds 4, 6, 10 and 12 were prepared from ethynyl and allenyl derivatives of self condensed cycloalkanones 3, 5, 9 and 11 by thermal oxy-Cope rearrangement is described.
Ring Enlargement-Annulation via Thermal Oxy-Cope Rearrangement
Janardhanam, Selvasekaran,Devan, Balachari,Rajagopalan, Krishnamoorthy
, p. 6761 - 6764 (2007/10/02)
Thermal oxy-Cope rearrangement of substrates 5,7 and 11 resulted in ring expansion and annulation.The effect of alkene substituents and variation in the ring systems on the reaction has been studied.
SYNTHESIS OF A POTENTIAL STEROID INTERMEDIATE BY ANIONIC OXY-COPE REARRANGEMENT
Sathyamoorthi, G.,Thangaraj, K.,Srinivasan, P. C.,Swaminathan, S.
, p. 4427 - 4428 (2007/10/02)
The synthesis of the tricyclic ketol 6 which is a potential intermediate for non-aromatic steroids has been achieved via an anionic oxy-Cope rearrangement.
