97946-22-0Relevant academic research and scientific papers
Highly efficient two-step synthesis of C-sp3-centered geminal diiodides
Cloarec, Jean-Manuel,Charette, Andre B.
, p. 4731 - 4734 (2007/10/03)
(Chemical Equation Presented) Trisubstituted gem-diiodoalkenes of functionalized chains are efficiently reduced to the corresponding terminal geminal diiodides in high yields upon treatment with the diazene precursor, diethyl 4-(hydrazinosulfonyl)-benzyl phosphonate.
A Wittig-like Synthesis of 1,1-Di-iodoalkenes
Gavina, Francisco,Luis, Santiago V.,Ferrer, Patrick,Costero, Ana M.,Marco, J. Alberto
, p. 2843 - 2852 (2007/10/02)
The synthesis of 1,1-diiodoalkenes from aliphatic and aromatic aldehydes and triphenylphosphine-carbon tetraiodide is described.The reagent does not work with ketones.With aldehydes, yields are dependent on the electrophilicity of the carbonyl group.
1,1-Di-iodoalkenes from Aldehydes and Triphenylphosphine-Carbon Tetraiodide
Gavina, Francisco,Luis, Santiago V.,Ferrer, Patrick,Costero, Ana M.,Marco, J. Alberto
, p. 296 - 297 (2007/10/02)
The Wittig-like transformation of aliphatic and aromatic aldehydes into 1,1-di-iodoalkenes can be achieved with triphenylphosphine-carbon tetraiodide.
