97982-54-2Relevant academic research and scientific papers
Synthesis and Characterisation of Binuclear Silicon-Aluminium and Arsenic-Aluminium Complexes with Schiff Bases
Chaturvedi, Vibhav,Tandon, J. P.
, p. 422 - 424 (2007/10/02)
Trimethylsilyl acetate or phenylarsonic acid on reaction with aluminium isopropoxide yields two new series of complexes of the types, (CH3)3Si-O-Al(OPri)2 and .The isopropoxy groups in these derivatives further undergo facile reactions with bidentate Schiff bases giving coloured complexes of the types (CH3)3Si-O-Al(SB-H)2 and respectively, where SB-H is deprotonated form of the Schiff base.The Si-Al type of compounds are monomeric in nature and nonelectrolytes in DMF and DMSO, where the As-Al type of derivatives are insoluble in most of the organic solvents and appear to be polymeric in nature.A few compounds have been found to be quite effective as potential pesticides.
