97991-03-2Relevant academic research and scientific papers
Diastereoselective Michael Additions of Chiral Imidazolidines to Trityl Enones
Seebach, Dieter,Pfammatter, Elmar,Gramlich, Volker,Bremi, Tobias,Kuehnle, Florian,et al.
, p. 1145 - 1152 (2007/10/02)
The enolates A and C of t-butyl (R)-2-t-butyl-3-methyl-4-oxo-1-imidazolidinecarboxylate (1, Boc-BMI) and of 1-t-butyl 5-methyl (2R,5S)-2-t-butyl3-methyl-1,5-imidazolidinedicarboxylate (3) and t-butyl (R)-2-t-butyl-5-lithio-3-methyl-1-imidazolidinecarboxyl
Tritylketones and Tritylenones. Contribution to the Sterically Enforced Michael Addition and to the Diastereoselective Aldol Addition
Seebach, Dieter,Ertas, Muemtaz,Locher, Rita,Schweizer, W. Bernd
, p. 264 - 282 (2007/10/02)
Tritylketones are prepared from trityllithium and aldehydes, with subsequent CrO3 oxidation (Scheme 1, 2a-f).Tritylenones are obtained from the saturated ketones and aldehydes or ketones, preferably by (CH3)3Al-mediated aldol addition with subsequent dehy
