98014-28-9Relevant academic research and scientific papers
Synthesis and comparison of N-fluorobis[(perfluoroalkyl)sulfonyl]imides with different perfluoroalkyl groups
Zhang, Jie,Desmarteau, Darryl D.
, p. 253 - 257 (2007/10/03)
N-fluorobis[(perfluoroalkyl)sulfonyl]imides, CF3SO2N(F)SO2Rf (Rf′=C4F9, C6F13, C8F17) and (C4F9SO2)2NF, were prepared by direct fluorination of corresponding N-H compounds using elemental fluorine without a solvent in good to excellent yields. All of these N-F compounds are electrophilic fluorination agents and can easily deliver F+ to certain molecules. Their reactions with aromatic rings, beta-diketones, and alkenes were investigated to compare their fluorination power.
Electrophilic Fluorination of Unsaturated Systems with the Recently Developed Acetyl Hypofluorite
Rozen, Shlomo,Lerman, Ori,Kol, Moshe,Hebel, David
, p. 4753 - 4758 (2007/10/02)
Acetyl hypofluorite (AcOF, 1) is a relatively new reagent which is prepared in situ from F2 and is an excellent source for electrophilic fluorine.Unlike the other known fluoroxy reagents, it reacts smoothly and quickly at -78 deg C with many types of olef
