98014-46-1Relevant academic research and scientific papers
Unveiling latent α-iminocarbene reactivity for intermolecular cascade reactions through alkyne oxidative amination
Mace, Nina,Thornton, Aaron R.,Blakey, Simon B.
supporting information, p. 5836 - 5839 (2013/07/05)
Setting a trap: Described is the development of a metallonitrene-initiated alkyne oxidation cascade with intermolecular trapping of the reactive intermediate with a variety of allyl ethers to provide α-oxyimine products in which new Ci￡N, C-O, and C-C bonds have all been generated (see Scheme; tfacam=trifluoroacetamide). Copyright
