98014-47-2

Upstream product

• 98014-46-1 (E)-hept-5-en-3-yn-1-ol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 98014-48-3 tert-Butyl-[((3Z,5E)-hepta-3,5-dienyl)oxy]-diphenyl-silane 
• 590-13-6 (Z)-1-propenyl bromide 
• 88158-68-3 4-(tert-butyldiphenylsilyloxy)-1-butyne 

Downstream Products

• 98014-54-1 ethyl cis-1,2,3,4,4aβ,7,8,8aβ-octahydro-2-benzyl-7β-methyl-8-isoquinolinecarboxylate 
• 98014-53-0 ethyl 4-<1-N-benzyl-(Z,E)-3,5-heptadienyl>-2-butenoate 
• 98014-51-8 (Z,E)-N-benzyl-3,5-heptadien-1-amine 
• 98014-48-3 tert-Butyl-[((3Z,5E)-hepta-3,5-dienyl)oxy]-diphenyl-silane 

Relevant academic research and scientific papers

Synthesis of allenic diols by samarium, diiodide-promoted coupling between alkynyloxiranes and ketones

The SmI2-mediated reductive coupling between alkynyloxiranes and ketones provides a new route to 2,3-pentadiene-1,5-diols. The preferred stereochemistry observed in the coupling products is the result of the new C- C bond forming anti with respect to the opening epoxide ring. Yields and diastereoselectivities are dependent on the alkynyloxirane substitution pattern.

Stereocontrolled Synthesis of Cis-Fused Hydroisoquinolines by an Intramolecular Diels-Alder Reaction of (Z)-Dienes

An efficient stereocontrolled synthesis highly functionalized cis-fused octahydroisoquinolines via an intramolecular Diels-Alder reaction of (Z)-dienes is described.