98056-39-4Relevant academic research and scientific papers
HYDROBORATION OF UNSATURATED AMINES VIII A CONVENIENT SYNTHESIS OF AMINO-3 PROPANOL-1
Benmaarouf-Khallaayoun, Z.,Baboulene, M.,Speziale, V.,Lattes, A.
, p. 233 - 242 (2007/10/02)
A new route with increased yield and stereoselectivity is reported for the synthesis of amino-3 propanols-1.It involved a hydroboration-oxidation reaction using bora- 9 bicyclo nonane.The amino group was protected by a phosphorylated grouping giving rise to novel and potentially useful phosphorylated reagents.
HYDROBORATION D'AMINES INSATUREES. IX. ROLE D'UNE LIAISON PIV-N SUR LA COMPLEXATION AZOTE-BORE LORS DE LA REACTION D'HYDROBORATION D'AMINES N-ALLYLIQUES
Benmaarouf-Khallaayoun, Zahra,Baboulene, Michel,Speziale, Vincent,Lattes, Armand
, p. 309 - 318 (2007/10/02)
The amino group of N-allylic amines which is protected by a phosphorylated grouping hinders nitrogen-boron coordination and allows normal addition of the boron hydrides.The hydroboration-oxidation reaction of phosphorated N-allylic amines, by appropriate hydroboration agents, lead to N-phosphorated 3-aminopropanols with very good yields.
