98057-61-5Relevant academic research and scientific papers
Steric and electronic effects in the aryl phosphate to arylphosphonate rearrangement
Casteel,Peri
, p. 691 - 693 (2007/10/02)
A number of carboxy substituted aryl phosphates have been prepared and subjected to anionic rearrangement conditions to provide the corresponding phenolic phosphonates. Steric effects of the phosphate ester group and the electronic effects of the aryl car
REARRANGEMENT OF DI-T-BUTYL ARYL PHOSPHATES TO DI-T-BUTYL(2-HYDROXYARYL)PHOSPHONATES. PREPARATION OF (2-HYDROXY-1,3-PHENYLENE)BISPHOSPHONIC ACIDS
Dhavan, Balram,Redmore, Derek
, p. 177 - 182 (2007/10/02)
Di-t-butyl aryl phosphates 3 on treatment with lithium diisopropylamide rearrange to di-t-butyl (2-hydroxyaryl)phosphonates 5.A di-t-butyl (2-hydroxyaryl) phosphonate on reaction with di-t-butyl phosphorochloridate yields a phosphate-phosphonate 8 which o
