98088-49-4Relevant academic research and scientific papers
Use of a benzyl ether as a traceless hydrogen donor in the anti-Markovnikov hydrofunctionalization of alkenes with xanthates
Hayashi, Hirohito,Kaga, Atsushi,Wang, Bin,Gagosz, Fabien,Chiba, Shunsuke
supporting information, p. 7535 - 7538 (2018/07/13)
A new protocol for the anti-Markovnikov hydrofunctionalization of alkenyl alcohol O-Bn ethers was developed using xanthates as functionalizing agents in the presence of lauroyl peroxide as a radical initiator and a stoichiometric oxidant. The benzyl group serves as a traceless hydrogen donor in the remote radical hydrogen atom transfer event during the process.
Lewis acid-mediated acetal substitution reactions: Mechanism and application to asymmetric catalysis
Kobayashi, Sha,Arai, Kenzo,Yamakawa, Takeshi,Chen, Yi-Jing,Salter, Matthew M.,Yamashita, Yasuhiro
supporting information; experimental part, p. 1927 - 1932 (2011/10/08)
Substitution reactions of acetals with carbon nucleophiles are fundamental and conventional organic reactions. We succeeded in the preparation of an optically active acetal, which reacted with a silyl enol ether smoothly to afford the desired adducts in r
