1825-64-5Relevant articles and documents
Use of silyl ethers as fluoride scavengers in RNA synthesis
Song, Quanlai,Jones, Roger A.
, p. 4653 - 4654 (1999)
Use of a fluoride ion scavenger significantly simplifies isolation of synthetic RNA.
New methods of synthesis of boron, germanium, and tin derivatives of pentavalent phosphorus thioacids
Nizamov, Il'yas S.,Sorokina, Tat'yana P.,Nizamov, Il'nar D.,Galimullina, Nailya G.,Batyeva, Elvira S.,Alfonsov, Vladimir A.
, p. 27 - 35 (2002)
The reaction of S-trimethysilyl esters of S-propyl-4-methoxyphenyltrithiophosphonic, bis-(dialkylamido)dithiophosphoric, and S-ethyl-diethylamidotrithiophosphoric acid with trialkyl borates, triorganylbromogermanes, trimethyl(isobutylthio)germane, and tri
Buerger et al.
, p. 292,295, 300 (1964)
Novel protocol for the synthesis of organic ammonium tribromides and investigation of 1,1′-(Ethane-1,2-diyl)dipiperidinium bis(tribromide) in the silylation of alcohols and thiols
Dey, Rupa R.,Paul, Bappi,Dhar, Siddhartha S.,Bhattacharjee, Sushmita
supporting information, p. 1545 - 1547 (2015/02/19)
A novel and efficient protocol for the synthesis of organic ammonium tribromides (OATBs) is developed by using inexpensive and eco-friendly periodic acid as an oxidant for the conversion of Br-to Br3-. The method does not use any mineral acid and metal oxidants. The protocol is utilized to synthesize a new bis(tribromide) viz., 1,1′-(ethane-1,2-diyl)dipiperidinium bis(tribromide) (EDPBT). EDPBT is investigated as a catalyst in the silylation of alcohols and thiols by HMDS (hexamethyldisilazane) under solvent-free conditions.
Polystyrene-gallium trichloride complex: A mild, highly efficient, and recyclable polymeric lewis acid catalyst for chemoselective silylation of alcohols and phenols with hexamethyldisilazane
Rahmatpour, Ali,Vakili, Ali,Azizian, Setare
, p. 443 - 451 (2013/12/04)
Polystyrene-supported gallium trichloride (PS/GaCl3) as a highly active and reusable heterogeneous Lewis acid effectively activates hexamethyldisilazane (HMDS) for the efficient silylation of alcohols and phenols at room temperature. In this he