98119-26-7

Upstream product

• 97775-32-1 dichlorobis(2,6-dimethyl-4-bromophenyl isocyanide)palladium(II) 
• 52522-40-4 tris(dibenzylideneacetone)dipalladium⁽⁰⁾ * CHCl₃ 
• 97775-32-1 dichlorobis(4-bromo-2,6-xylyl isocyanide)palladium(II) 
• 24139-49-9 5-bromo-2-isocyano-1,3-dimethylbenzene 

Relevant academic research and scientific papers

Dichlorotetrakis(isocyanide)dipalladium(I) Containing a Metal-Metal Bond

The structure of 2> has been determined by X-ray diffraction.A metal-metal bond joins two Pd atoms, each of which possesses an essentially square-planar coordinate site.The photochemical reaction of 2> in CH2Cl2 led to a cleav

Electrochemical Preparation of Tetrakis(isocyanide)dipalladium(I) Dichloride

The electrochemical behavior of PdCl2(RNC)2 (1) has been investigated in acetonitrile at Pt and Hg electrodes.The cyclic voltammogram of 1 showed a reduction wave at ca -1.2 V, corresponding to a two-electron transfer.Coulometric reduction of 1 at the Pt electrode gave a binuclear complex, Pd2Cl2(RNC)4 (2).A similar reaction at the Hg electrode gave 2 in a relatively low yield.A Pt electrode was superior to a Hg one in the electrochemical synthesis of 2.The polarogram of 1 at a Hg electrode suggested a CE mechanism of the electrode ration.