98161-38-7Relevant academic research and scientific papers
Template Synthesis of a New P2N2 Macrocyclic Ligand via Direct Alkylation of Co-ordinated Amido Nitrogen Atoms; X-Ray Structure Analysis of the Free Ligand and its Neutral Ni(II) Complex
Ansell, Christopher W. G.,Cooper, Mervyn K.,Dancey, Keith P.,Duckworth, Paul A.,Henrick, Kim,et al.
, p. 439 - 441 (1985)
The dication (2+), (1), propane, meso-L1> on deprotonation gives the neutral complex, , (2), with a cis-disposition of the two amido groups which undergo facile alkylation with propane-1,3-ditoluene-p-sulphonate to give , (3), a complex of the new P2N2 macrocycle meso-L2; X-ray structure analyses of the nitrate salt of (1), L2, and (3) confirm the meso-configuration of the ligands.
