Template Synthesis of a New P2N2 Macrocyclic Ligand via Direct Alkylation of Co-ordinated Amido Nitrogen Atoms; X-Ray Structure Analysis of the Free Ligand and its Neutral Ni(II) Complex

DOI: 10.1039/c39850000439

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 439 - 441 (1985)

Update date:2022-09-26

Topics:

Authors:

Ansell, Christopher W. G.

Cooper, Mervyn K.

Dancey, Keith P.

Duckworth, Paul A.

Henrick, Kim

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850000439

The dication (2+), (1), propane, meso-L1> on deprotonation gives the neutral complex, , (2), with a cis-disposition of the two amido groups which undergo facile alkylation with propane-1,3-ditoluene-p-sulphonate to give , (3), a complex of the new P2N2 macrocycle meso-L2; X-ray structure analyses of the nitrate salt of (1), L2, and (3) confirm the meso-configuration of the ligands.

Full text of DOI:10.1039/c39850000439

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Pt(NC₆H₄P(C₆H₅)(CH₂)3P(C₆H₅)C₆H₄N(CH₂)3)

Cas No:98161-38-7

R&D Labs maybe for 98161-38-7

Quzhou Aokai Chemical Co., Ltd.

Contact:86-570-3032832

Address:NO.16 , Laodong Road,Quzhou City, Zhejiang Province,China
Huzhou City Linghu Xinwang Chemical Co.,Ltd.

Contact:86-572-3948695/3945236

Address:huzhou
SHIJIAZHUANG CHENSHI IMPORT AND EXPORT CO.,LTD

Contact:+86-311-89871056

Address:RM2017 BUILDING CTIANSHAN GALAXY PLAZA,NO168 CHANGJIANG ROAD,GAOXIN DISTRICT,SHIJIAZHUANG CITY, HEBEI,CHINA
Shanghai Kangxin Chemical Co., Ltd

Contact:+86 21 60717227

Address:118,Ganbai Village,Waigang Town,Jiading District,Shanghai
Shanghai Yuanye Bio-Technology Co., Ltd.

website:http://www.shyuanye.com

Contact:+86-21-61845781

Address:Building 6, No. 465, Changta Road,Songjiang District,Shanghai,China

Relevant to this article

Synthesis of Linear α,β-Unsaturated Amides from Isocyanates and Alkenylaluminum Reagents

Doi:10.1055/s-0037-1610753
(2020)
Microwave-assisted one-step synthesis of acetophenones via palladium-catalyzed regioselective arylation of vinyloxytrimethylsilane

Doi:10.1002/adsc.201200334
(2012)
Practical and Selective sp³ C?H Bond Chlorination via Aminium Radicals

Doi:10.1002/anie.202100030
(2021)
Synthesis and hybridization properties of oligodeoxynucleotides with long-chain linkers

Doi:10.1002/hlca.200790203
(2007)
Biosynthetic tailoring of microcin E492m: Post-translational modification affords an antibacterial siderophore-peptide conjugate

Doi:10.1021/ja074650f
(2007)
One-Pot Synthesis of Substituted Benzo[b]furans and Indoles from Dichlorophenols/Dichloroanilines Using a Palladium-Dihydroxyterphenylphosphine Catalyst

Doi:10.1021/acs.joc.6b00824
(2016)

Article Doi