Template Synthesis of a New P2N2 Macrocyclic Ligand via Direct Alkylation of Co-ordinated Amido Nitrogen Atoms; X-Ray Structure Analysis of the Free Ligand and its Neutral Ni(II) Complex

DOI: 10.1039/c39850000439

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 439 - 441 (1985)

Update date:2022-09-26

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Authors:

Ansell, Christopher W. G.

Cooper, Mervyn K.

Dancey, Keith P.

Duckworth, Paul A.

Henrick, Kim

et al. et al.

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Article abstract of DOI:10.1039/c39850000439

The dication (2+), (1), propane, meso-L1> on deprotonation gives the neutral complex, , (2), with a cis-disposition of the two amido groups which undergo facile alkylation with propane-1,3-ditoluene-p-sulphonate to give , (3), a complex of the new P2N2 macrocycle meso-L2; X-ray structure analyses of the nitrate salt of (1), L2, and (3) confirm the meso-configuration of the ligands.

Full text of DOI:10.1039/c39850000439

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