98168-73-1

Upstream product

• 98095-65-9 Benzoic acid (2R,3S,4R,5S)-2-((S)-1-iodo-ethyl)-4-(2-methoxy-ethoxymethoxy)-2,4,5-trimethyl-tetrahydro-furan-3-yl ester 
• 107613-13-8 Benzoic acid (Z)-(R)-1-[(1R,2S)-2-benzyloxy-1-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-but-2-enyl ester 
• 98095-65-9 Benzoic acid (2R,3S,4R,5S)-2-(1-iodo-ethyl)-4-(2-methoxy-ethoxymethoxy)-2,4,5-trimethyl-tetrahydro-furan-3-yl ester 
• 98095-59-1 (+/-)-(3R^*,4R^*)-4-(benzyloxy)-3-methyl-1-penten-3-ol 
• 110510-53-7 (+/-)-(3R^*,4R^*)-4-(benzyloxy)-3-<(2-methoxyethoxy)methoxy>-3-methyl-1-pentene 
• 107613-12-7 (Z)-(4R,5S,6S)-6-Benzyloxy-5-(2-methoxy-ethoxymethoxy)-3,5-dimethyl-hept-2-en-4-ol 
• 98-88-4 benzoyl chloride 
• 98095-63-7 (2R,3S,4S,5R)-2-((S)-1-Iodo-ethyl)-4-(2-methoxy-ethoxymethoxy)-2,4,5-trimethyl-tetrahydro-furan-3-ol 
• 110510-54-8 (+/-)-(2S^*,3R^*)-3-(benzyloxy)-2-<(2-methoxyethoxy)methoxy>-2-methyl-1-butanal 

Relevant academic research and scientific papers

Total Synthesis of (+/-)-Citreoviridin

Investigations of iodine-induced cyclizations of γ,δ-olefinic benzyl ethers have led to highly substituted tetrahydrofurans from acyclic precursors with excellent stereochemical control.Our studies have afforded total syntheses of two fungal metabolites,

STUDIES OF TETRASUBSTITUTED TETRAHYDROFURANS

Unambiguous stereochemical assignments, detailing the course of iodine-induced cyclizations of the γ,δ-olefinic benzyl ethers 3ab, are available from X-ray studies.Pure samples of all four diastereomeric tetrahydrofuran alcohols 8, 9, 12, and 15 have been

HYDROXYL-DIRECTED IODOETHERIFICATIONS OF ALLYLIC ALCOHOLS. SYNTHESIS OF ALLYLIC ALCOHOLS. SYNTHESSIS OF (+/-)-CITREOVIRAL.

Iodine-induced cyclizations of γ,δ-olefinic benzyl ethers have afforded highly substituted tetrahydrofurans with complete stereocontrol as directed by the configuration of an allylic alcohol.Evidence for stereochemical assignments and conversion to citreo