982-45-6Relevant academic research and scientific papers
Iron-mediated cross dehydrogenative coupling (CDC) of terminal alkynes with benzylic ethers and alkanes
Xiang, Shi-Kai,Zhang, Bo,Zhang, Li-He,Cui, Yuxin,Jiao, Ning
experimental part, p. 50 - 54 (2012/03/12)
Iron-mediated sp-sp3 C-C bond formation through the cross dehydrogenative coupling (CDC) of terminal alkynes with benzylic ethers or alkanes has been developed. The inexpensive iron salt is used as the catalyst to make this transformation envir
Copper-catalyzed cross-dehydrogenative coupling (CDC) of Alkynes and Benzylic C-H bonds
Correia, Camille A.,Li, Chao-Jun
supporting information; experimental part, p. 1446 - 1450 (2010/08/20)
The activation of benzylic C-H bonds and subsequent coupling with terminal alkynes in the presence of 2,3-dichloro-5,6-dicyanoquinone (DDQ) and a catalytic amount of copper(I) triflate is presented. Good to moderate yields of disubstituted alkynes are obtained for this cross-dehydrogenative coupling (CDC) reaction between a variety of aromatic alkynes and diphenylmethane derivatives.
Sp-sp3 C-C bond formation via Fe(OTf)3/TfOH cocatalyzed coupling reaction of terminal alkynes with benzylic alcohols
Xiang, Shi-Kai,Zhang, Li-He,Jiao, Ning
supporting information; experimental part, p. 6487 - 6489 (2010/03/04)
An Fe(OTf)3/TfOH cocatalyzed sp-sp3 C-C bond formation through the coupling of benzylic alcohols with terminal alkynes in the absence of base has been developed. H2O is the sole by-product.
