98230-44-5Relevant articles and documents
Alkylative Epoxide Rearrangement. A Stereospecific Approach to Chiral Epoxide Pheromones
Bell, Thomas W.,Ciaccio, James A.
, p. 5153 - 5162 (2007/10/02)
The alkylative rearrangement of 1,2-epoxy-3-alkanol tosylates is applied to the synthesis of chiral epoxide pheromones.Attack at the terminal carbon atom of epoxy tosylates by lithioacetylenes and cyclization of the intermediate tosyloxy alcohols produces
SYNTHESIS OF (6Z)-CIS-9S,10R-EPOXYHENEICOSENE, A COMPONENT OF THE RUBY TIGER MOTH PHEROMONE
Rollin, Patrick,Pougny, Jean-Rene
, p. 3479 - 3490 (2007/10/02)
A 10-step synthesis of the titled pheromone and analogues from an acyclic derivative of D-Xylose is described.