98273-77-9Relevant academic research and scientific papers
Metal- and Acid-Free C-H Formylation of Nitrogen Heterocycles: Using Trioxane as an Aldehyde Equivalent Enabled by an Organic-Soluble Oxidant
Ganley, Jacob M.,Christensen, Melodie,Lam, Yu-Hong,Peng, Zhengwei,Angeles, Angie R.,Yeung, Charles S.
, p. 5752 - 5756 (2018/09/21)
A metal-free, innate, and practical C-H formylation of nitrogen heterocycles using trioxane as a formyl equivalent is reported. This reaction provides a mild and robust method for modifying medicinally relevant heterocycles with an aldehyde handle. The use of an organic soluble oxidant, tetrabutylammonium persulfate, is critical in promoting the desired coupling.
Oxime O-ether compounds and fungicides for agricultural and horticultural use
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, (2008/06/13)
The present invention relates to novel oxime O-ether compounds represented by a general formula [I]; wherein R1represents C1-6alkyl, C3-6cycloalkyl, C1-6alkoxy, etc., m represents an integer of 1 to 4, R2/
OXIME ETHER COMPOUND AND AGRICULTURAL OR HORTICULTURAL BACTERICIDE
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Page/Page column 37, (2010/02/07)
An oxime ether compound represented by the formula [I] or a salt thereof which have excellent bactericidal activity and are useful as an agricultural or horticultural fungicide. [I] (In the formula, R1 represents halogeno, hydroxy, C1-6 alkyl, C1-6 haloalkyl, C1-6 alkoxy, C1-6 alkyl substituted by C1-6 alkoxy, cyano, nitro, C2-6 alkenyl, C2-6 haloalkenyl, C2-6 alkynyl, amino, mono(C1-6 alkyl)amino, di(C1-6 alkyl)amino, C3-6 cycloalkyl, carboxyl, C1-6 alkoxycarbonyl, etc.; R2 represents hydrogen, C1-6 alkyl, C3-6 cycloalkyl, C1-6 haloalkyl, etc.; R3 and R4 each represents hydrogen or C1-6 alkyl; k is an integer of 1 to 4; and A represents the heterocyclic group shown in the description.)
