98274-02-3

Basic information

• Product Name: p-chlorophenyl chloromethanesulfonate
• CAS NO: 98274-02-3
• Molecular Weight: 241.095
• Mol File: 98274-02-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: p-chlorophenyl chloromethanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: p-chlorophenyl chloromethanesulfonate(98274-02-3)
• EPA Substance Registry System: p-chlorophenyl chloromethanesulfonate(98274-02-3)

Safety Data

• Hazardous Substances Data: 98274-02-3(Hazardous Substances Data)

Upstream product

• 3518-65-8 monochloromethanesulfonyl chloride 
• 106-48-9 4-chloro-phenol 
• 6317-27-7 p-chlorophenyl mesylate 

Downstream Products

• 138373-09-8 p-Tolylsulfanyl-methanesulfonic acid 4-chloro-phenyl ester 
• 152482-36-5 p-chlorophenyl dichloromethanesulfonate 

Relevant articles and documents

Sulfonyl esters. 3. The formation of sulfone-sulfonates in the reactions of aryl methanesulfonates with sodium borohydride

Sodium hydride reductions of aryl methanesulfonates afford dimeric sulfone-sulfonate esters as well as products arising from SO bond rupture.SO bond rupture becomes more competitive as the LUMO energy of the sulfonate ester declines.Exploration of the chemistry of a sulfone-sulfonate ester revealed a complex novel reaction that resulted in the formation of, inter alia, a dichloromethanesulfonate ester and a trichloromethanesulfonate aster.The first succesful approaches to the synthesis of the heretofore unknown trichloromethanesulfonates and dichloromethanesulfonates are reported.Key words: sodium hydride reductions, sulfenes, sulfone-sulfonate esters.