98492-00-3Relevant academic research and scientific papers
Indium-mediated debromination of gem -bromonitroalkanes under mild conditions in aqueous medium
Acúrcio, Rita C.,Soengas, Raquel G.,Silva, Artur M. S.
supporting information, p. 1561 - 1564 (2014/07/08)
gem-Bromonitroalkanes are efficiently reduced into the corresponding dehalogenated products in excellent yields with indium metal in the presence of a palladium(0) catalyst and indium(III) chloride in aqueous medium. The addition of bromonitromethane to c
A catalytic highly enantioselective direct synthesis of 2-bromo-2-nitroalkan-1-ols through a Henry reaction
Blay, Gonzalo,Hernandez-Olmos, Victor,Pedro, Jose R.
supporting information; experimental part, p. 4840 - 4842 (2009/03/12)
Highly enantiomerically enriched 2-bromo-2-nitroalkan-1-ols are prepared by direct condensation of aliphatic and aromatic aldehydes with bromonitromethane in the presence of a catalytic amount of copper(ii) acetate and a C 1-symmetric camphor-d
A convenient samarium-promoted synthesis of aliphatic (E)-nitroalkenes under mild conditions
Concellon, Jose M.,Bernad, Pablo L.,Rodriguez-Solla, Humberto,Concellon, Carmen
, p. 5421 - 5423 (2008/02/08)
(Chemical Equation Presented) A samarium-promoted synthesis of (E)-nitroalkenes from 1-bromo-1-nitroalkan-2-ols in high yields and with total selectivity is reported. This reaction together with the easy and efficient preparation of the 1-bromo-1-nitroalk
Efficient addition reaction of bromonitromethane to aldehydes catalyzed by Nal: A new route to 1-bromo-1-nitroalkan-2-ols under very mild conditions
Concellon, Jose M.,Rodriguez-Solla, Humberto,Concellon, Carmen,Garcia-Granda, Santiago,Diaz, M. Rosario
, p. 5979 - 5982 (2007/10/03)
(Chemical Equation Presented) A catalytic Nal-mediated novel synthesis of 1-bromo-1-nitroalkan-2-ols was carried out by reaction of bromonitromethane with a variety of aldehydes, under very mild conditions. When the reaction was, performed with chiral N,N
