98510-12-4Relevant academic research and scientific papers
Chiral Induction in Photochemical Reactions. 10. The Principle of Isoinversion: A Model of Stereoselection Developed from the Diastereoselectivity of the Paterno-Buechi Reaction
Buschmann, Helmut,Scharf, Hans-Dieter,Hoffmann, Norbert,Plath, Martin Wolfgang,Runsink, Jan
, p. 5367 - 5373 (2007/10/02)
In the Paterno-Buechi reaction of the chiral phenylglyoxalates a-c with cyclic olefins 3-6, the diastereomeric oxetanes 3-6a-c and 3-6a'-c' are formed endo-phenyl selectively in high yields.The temperature dependence of the diastereoselectivity yields two
