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Tristannirane, hexakis[2,4,6-tris(1-methylethyl)phenyl]-, also known as hexakis[2,4,6-tris(tert-butyl)phenyl]tristannane, is a complex organotin compound with the chemical formula C36H54Sn3. It is a white crystalline solid that is insoluble in water but soluble in organic solvents. Tristannirane, hexakis[2,4,6-tris(1-methylethyl)phenyl]- is characterized by its hexagonal structure, with each vertex occupied by a tin atom, and each tin atom bonded to three 2,4,6-tris(tert-butyl)phenyl groups. These bulky tert-butyl groups provide steric hindrance, which can affect the compound's reactivity and stability. Tristannirane, hexakis[2,4,6-tris(1-methylethyl)phenyl]-, is primarily used in the field of materials science, particularly in the synthesis of certain polymers and as a catalyst in various chemical reactions. Due to its unique structure and properties, it has potential applications in the development of new materials with specific electronic, optical, or mechanical properties.

98526-67-1

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98526-67-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 98526-67-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,8,5,2 and 6 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 98526-67:
(7*9)+(6*8)+(5*5)+(4*2)+(3*6)+(2*6)+(1*7)=181
181 % 10 = 1
So 98526-67-1 is a valid CAS Registry Number.

98526-67-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name bis[2,4,6-tri(propan-2-yl)phenyl]tin

1.2 Other means of identification

Product number -
Other names Tristannirane,hexakis[2,4,6-tris(1-methylethyl)phenyl]

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:98526-67-1 SDS

98526-67-1Relevant academic research and scientific papers

From organotin hydrides to heteronuclear main group metal compounds: isolation of the first neutral bismuth/tin clusters

Steller, Beate G.,Flock, Michaela,Fischer, Roland C.

, p. 10095 - 10098 (2021)

From conversions of Ar2SnH2(Ar = Tripp, Dipp; Tripp = 2,4,6-Triisopropylphenyl, Dipp = 2,6-Diisopropylphenyl), and a bismuth(iii) amide, Bi[N(SiMe3)2]3, we isolated the first representatives of mixed, uncharged Bi/Sn clusters, Bi8Sn3Ar6. Along with unprecedented bicyclo[2.2.0]hexanes, (HAr2Sn)2Sn2Bi4, these have been characterized by single crystal X-Ray diffraction, heteronuclear NMR, vibrational and UV-Vis spectroscopy. Quantum-chemical calculations were carried out in order to understand bonding within the isolated polyhedral compounds.

Tetraarylstannagermene: A molecule with a Ge=Sn double bond

Schaefer, Annemarie,Saak, Wolfgang,Weidenbruch, Manfred

, p. 215 - 217 (2008/10/08)

A study was conducted on a molecule with a Ge=Sn double bond. The treatment of R2Ge=SnR2 with dry oxygen yielded a 3,4-germastannadioxetane with a stretched O-O bond length. It was found that the four-membered heterocyclic ring was folded from the torsion angle Ge-O-O-Sn of 31.4°.

A simplified, high-yield synthesis, and crystal structure of >

Brady, Fergal J.,Cardin, Christine J.,Cardin, David J.,Convery, Maire A.,Devereus, Michael M.,Lawless, Gerard A.

, p. 199 - 203 (2007/10/02)

The species iPr3-2,4,6)2>3> has been obtained in a simple, essentially quantitative, synthesis from SnCl2 and ArLi in diethyl ether at low temperature.The crystal structure analysis confirms the trimeric nature of the molecular units but reveals some unusual features.The crystal contains the unusual feature of an asymmetric unit that consists of three units of 3> in P21/c; the molecular unit is a scalene triangle, showing high consistency between the three molecules, in contrast to analogous trimeric species of silicon or germanium.The Sn-Sn bonds are lengthened (average value 2.942 Angstroem) owing to steric crowding.

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