98526-68-2

Upstream product

• 98526-67-1 hexakis(2,4,6-tri-isopropylphenyl) cyclotristannane 

Downstream Products

• 126857-72-5 ((2,4,6-iPr₃C₆H₂)2Sn)2S 
• 133777-56-7 (2,4,6-iPr₃C₆H₂)4 1,3-ditelluradistannetane 
• 133777-55-6 (2,4,6-iPr₃C₆H₂)4 telluradistannirane 
• 98526-67-1 hexakis(2,4,6-tri-isopropylphenyl) cyclotristannane 
• 134391-64-3 ((2,4,6-iPr₃C₆H₂)2Sn)2Se 
• 134391-65-4 ((2,4,6-iPr₃C₆H₂)2Sn)2Se₂ 
• 137947-36-5 1,1,2,2-tetrakis(2,4,6-triisopropylphenyl)-3-phenyl-1,2-distannacyclobutene 
• 176692-83-4 [Ru₃Sn₃(CO)9(C₆H₂(C₃H₇)3)6] 
• 176692-78-7 [Ru₃Sn₃(CO)9(CH(Si(CH₃)3)2)4(C₆H₂(C₃H₇)3)2] 
• 134391-62-1 (2,4,6-triisopropylbenzene)4(1,2-dithiadistannetane) 
• 126857-71-4 2,2,4,4-tetra(2,4,6-tri-isopropylphenyl)-1,3-dithia-2,4-stannetane 

Relevant academic research and scientific papers

A tetraaryldigermene with a short germanium-germanium double bond and a nearly planar environment of both germanium atoms

Treatment of GeCl2 ·dioxane with the Grignard reagent RMgBr (R = 2-rBu-4,5.6-Me3C6H) furnishes the tetraaryldigermene R2Ge=GeR2 (8). X-ray structure-analysis of 8 reveals a short Ge=Ge double bond, a nearly planar environment of both germanium atoms and extremely widened C-Ge-C angles of 128°. In solution, 8 dissociates into two germylene molecules R2Ge: which can be trapped with oxygen or by [4 + 1] cycloaddition reactions with 1,4-dihetero1,3-dienes. A similar cycloadduct of a stannylene was obtained by thermolysis of (R′2Sn)3 (R′ = 2,4,6-JPr3C6H2), in the presence of a 1,4-diazabutadiene and characterized by an Xray structure-analysis. VCH Verlagsgesellschaft mbH.

SMALL RINGS WITH AND WITHOUT TIN-TIN BONDS

Thermolysis of hexakis(2,4,6-triisopropylphenyl)cyclotristannane 1 generates tetrakis(2,4,6-triisopropylphenyl)distannene 3 which can be trapped by various reagents.Addition of phenylacetylene to 3 yields a 1,2-distannacyclobutene derivative.Reaction of 3 with tellurium and selenium leads to tellura- and selenadistanniranes, 7,9, with an excess of these chalcogens the 1,3-dichalcogenadistannetanes, 8, 10, are formed.With elemental sulfur the 1,3-dithiadistannetane 12 along with the 1,2-dithiadistannetane 13 is formed.Thiadistannirane 11, which is not accessible by this route, is, however, smoothly obtained by reaction of 3 with methylthiirane.