98607-02-4

Basic information

• Product Name: 2-methylpropaneselenoic acid Se-phenyl ester
• Synonyms: 2-methylpropaneselenoic acid Se-phenyl ester
• CAS NO: 98607-02-4
• Molecular Weight: 227.165
• Mol File: 98607-02-4.mol

Chemical Properties

• CAS DataBase Reference: 2-methylpropaneselenoic acid Se-phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methylpropaneselenoic acid Se-phenyl ester(98607-02-4)
• EPA Substance Registry System: 2-methylpropaneselenoic acid Se-phenyl ester(98607-02-4)

Safety Data

• Hazardous Substances Data: 98607-02-4(Hazardous Substances Data)

Upstream product

• 5707-04-0 Phenylselenyl chloride 
• 79-31-2 isobutyric Acid 
• 41924-21-4 phenyl tributylstannyl selenide 
• 79-30-1 isobutyryl chloride 
• 346724-30-9 1-(1H-benzo[d][1,2,3]triazol-1-yl)-2-methylpropan-1-one 
• 1666-13-3 diphenyl diselenide 
• 114953-80-9 2,2,2-trifluoro-1-(phenylselanyl)ethanol 
• 1092379-00-4 C₁₀H₇F₇OSe 
• 1092378-99-8 2,2,3,3,3-pentafluoro-1-(phenylselanyl)propanol 

Downstream Products

• 359792-06-6 1-(tert-Butyldimethylsiloxy)-1-phenylselanyl-2-methyl-1-propene 

Relevant articles and documents

Acylation of diselenides and disulfides with N-acylbenzotriazoles promoted by SmI2

The acylation of diselenides or disulfides with N-acylbenzotriazoles mediated by SmI2 has been achieved successfully without the presence of HMPA, and the corresponding selenolesters or thioesters have been prepared in good yields.

Investigation on the se-acylation with N-acylbenzotriazoles

The acylation of Se-nucleophiles with N-acylbenzotriazoles was investigated. Samarium phenylselenolate and benzylselenolate (RSeSmI 2) reacted with N-aroyl and N-alkanoylbenzotriazoles smoothly and afforded the corresponding selenol esters in g

Indium-mediated cleavage of diphenyl diselenide and diphenyl disulfide: efficient one-pot synthesis of unsymmetrical diorganyl selenides, sulfides, and selenoesters

A convenient and efficient method was developed for the synthesis of alkyl phenyl selenides, sulfides, and selenoesters in one-pot reaction by using indium metal. The reaction showed the selectivity for tert-alkyl, benzylic, and allylic halides over primary and secondary alkyl halides. For the reaction of primary and secondary alkyl iodides and bromides, the yields of selenides were improved by the addition of a catalytic amount of iodine.

1-(organoselanyl)perfluoroalkanols: A stable and efficient precursor for organoselenols

The 1-(organoselanyl)perfluoroalkanols 1, 3, 4, and 10 were successfully prepared and reactions with hexanoyl chlorides to produce the corresponding esters 5, 7, and 8, accompanied by the selenoesters 6 were conducted. The DBU-mediated alkylations of the heptafluorobutanols 4, 10, and the α-p-nitro-benzoate 2 with alkyl halides easily provided alkyl phenyl selenides 9a-9i and 11a-11c in good to high yields. Copyright

Phenyl tributylstannyl selenide as a promising reagent for introducion of the phenylseleno group

A new synthetic method of organoselenium compounds has been developed. When phenyl tributylstannyl selenide (PhSeSnBu3) was allowed to react with acyl or aroyl chlorides in the presence of a catalytic amount of a palladium complex such as Pd(PPh3)4, Se-phenyl selenol esters were obtained in moderate to good yields. Similarly, the palladium complex catalyzed the reaction of PhSeSnBu3 with α-halo carbonyl compounds to afford the corresponding α-phenyseleno carbonyl compounds in moderate yields.