98674-98-7

Upstream product

• 128013-81-0 (1S,4R)-2-[(E)-(R)-2-(4-Methoxy-phenyl)-1-phenyl-ethylimino]-7,7-dimethyl-bicyclo[2.2.1]heptane-1-carboxylic acid (2-hydroxy-phenyl)-amide 
• 100-46-9 benzylamine 
• 127498-25-3 10-(N-o-hydroxyphenylamide)-N-benzyl-7,7-dimethyl-dicyclo-<2,2,1>-heptane-2-imine 

Relevant academic research and scientific papers

ASYMETRIC SYNTHESIS X: THE HIGH ENANTIOSELECTIVE SYNTHESIS OF (R)-α-SUBSTITUTED BENZYLIC AMINES VIA THE MODIFIED (+)-CAMPHOR DERIVATIVE AS CHIRAL SYNTHON

A new chiral synthon-10-substituted (+)-camphor derivative (III) is synthesized.The alkylation of the (III) with a variety of alkylating agents gives the high enantioselectivity ranging from 72-100percent e.e..And the crystal structures of the (III) and (IV) are involved in explaining the results.