127498-25-3

Upstream product

• 127498-24-2 (1S,4R)-7,7-Dimethyl-2-oxo-bicyclo[2.2.1]heptane-1-carboxylic acid (2-hydroxy-phenyl)-amide 
• 100-46-9 benzylamine 

Downstream Products

• 128013-79-6 (1S,4R)-7,7-Dimethyl-2-[(E)-(R)-2-methyl-1-phenyl-propylimino]-bicyclo[2.2.1]heptane-1-carboxylic acid (2-hydroxy-phenyl)-amide 
• 128013-81-0 (1S,4R)-2-[(E)-(R)-2-(4-Methoxy-phenyl)-1-phenyl-ethylimino]-7,7-dimethyl-bicyclo[2.2.1]heptane-1-carboxylic acid (2-hydroxy-phenyl)-amide 
• 6668-27-5 (S)-2-methyl-1-phenylpropane-1-amine 
• 98674-98-7 (R)-2-(4-Methoxy-phenyl)-1-phenyl-ethylamine 
• 23459-35-0 R-α-cyclohexylbenzylamine 
• 6668-27-5 (R)-2-methyl-1-phenylpropylamine 
• 3082-58-4 (S)-1,2-diphenylethyl amine 
• 34645-25-5 (R)-(-)-1,2-diphenylethylamine 
• 3886-69-9 (R)-1-phenyl-ethyl-amine 
• 2627-86-3 (S)-1-phenyl-ethylamine 
• 128013-80-9 (1S,4R)-7,7-Dimethyl-2-[(E)-(R)-1-phenyl-ethylimino]-bicyclo[2.2.1]heptane-1-carboxylic acid (2-hydroxy-phenyl)-amide 
• 128013-82-1 (1S,4R)-2-[(E)-(R)-1,2-Diphenyl-ethylimino]-7,7-dimethyl-bicyclo[2.2.1]heptane-1-carboxylic acid (2-hydroxy-phenyl)-amide 
• 128013-83-2 (1S,4R)-2-[(E)-(R)-Cyclohexyl-phenyl-methylimino]-7,7-dimethyl-bicyclo[2.2.1]heptane-1-carboxylic acid (2-hydroxy-phenyl)-amide 

Relevant academic research and scientific papers

ASYMETRIC SYNTHESIS X: THE HIGH ENANTIOSELECTIVE SYNTHESIS OF (R)-α-SUBSTITUTED BENZYLIC AMINES VIA THE MODIFIED (+)-CAMPHOR DERIVATIVE AS CHIRAL SYNTHON

A new chiral synthon-10-substituted (+)-camphor derivative (III) is synthesized.The alkylation of the (III) with a variety of alkylating agents gives the high enantioselectivity ranging from 72-100percent e.e..And the crystal structures of the (III) and (IV) are involved in explaining the results.