98771-00-7Relevant academic research and scientific papers
DIASTEREO- AND ENANTIOSELECTIVE PREPARATION OF β-ALKYLHOMOALLYLIC ALCOHOLS SYNTHESIS OF SERRICORNIN AND CORYNOMYCOLIC ACID
Kobayashi, Yuichi,Kitano, Yasunori,Takeda, Yoshiyuki,Sato, Fumie
, p. 2937 - 2944 (2007/10/02)
A new and efficient method for the preparation of four possible stereoisomers of β-alkylhomoallylic alcohols 1 has been developed which is based on the diastereoselective addition of nucleophiles to optically active α-alkyl-β-trimethylsilyl-β,γ-unsaturate
Acyclic Stereoselection using 1,2-Asymmetric Induction. The First Total Synthesis of (+)-Corynomycolic Acid
Kitano, Yasunori,Kobayashi, Yuichi,Sato, Fumie
, p. 498 - 499 (2007/10/02)
The first total synthesis of (+)-corynomycolic acid (1), which includes as the key step, diastereoselective reduction of the optycally active carbonyl compounds (8) is described.
