98815-79-3

Basic information

• Product Name: (2S,3S,3aS,9bR)-3-benzyloxy-2-benzyloxymethyl-3,3a,5,9b-tetrahydro-2H-furo<3,2-c><2>benzopyran
• CAS NO: 98815-79-3
• Molecular Weight: 402.49
• Mol File: 98815-79-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (2S,3S,3aS,9bR)-3-benzyloxy-2-benzyloxymethyl-3,3a,5,9b-tetrahydro-2H-furo<3,2-c><2>benzopyran(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S,3aS,9bR)-3-benzyloxy-2-benzyloxymethyl-3,3a,5,9b-tetrahydro-2H-furo<3,2-c><2>benzopyran(98815-79-3)
• EPA Substance Registry System: (2S,3S,3aS,9bR)-3-benzyloxy-2-benzyloxymethyl-3,3a,5,9b-tetrahydro-2H-furo<3,2-c><2>benzopyran(98815-79-3)

Safety Data

• Hazardous Substances Data: 98815-79-3(Hazardous Substances Data)

Upstream product

• 16838-89-4 2,3,5-tri-O-benzyl-D-ribofuranose 
• 86883-42-3 2,3,5-tris-O-(phenylmethyl)-β-D-ribofuranosyl fluoride 
• 55339-64-5 2,4-dimethyl-3-trimethylsilyloxy-2-pentene 
• 64363-77-5 methyl 2,3,5-tri-O-benzyl-D-ribofuranoside 
• 131615-65-1 methyl 2,3,5-tri-O-benzyl-α,β-L-arabinofuranoside 
• 131615-66-2 1-O-acetyl-2,3,5-tri-O-benzyl-L-arabinofuranose 
• 91110-24-6 Acetic acid (2S,3R,4R,5R)-3,4-bis-benzyloxy-5-benzyloxymethyl-tetrahydro-furan-2-yl ester 
• 58381-23-0 (3R,4R,5R)-3,4-bis(benzyloxy)-5-((benzyloxy)methyl)tetrahydrofuran-2-yl acetate 
• 96192-07-3 2,3,5-tri-O-benzyl-L-arabinofuranose 

Relevant articles and documents

A simple and ready internal C-glycosylation of 2,3,5-tri-O-benzylglycofuranoses promoted by the boron trifluoride-diethyl ether complex

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STRUCTURAL ELUCIDATION AND A NOVEL REDUCTIVE CLEAVAGE OF RIBOFURANOSYL RING C-1 - O BOND OF THE INTRAMOLECULAR C-ARYLATION PRODUCT OF TRI-O-BENZYL-β-D-RIBOFURANOSYL FLUORIDE

Treatment of 2,3,5-tri-o-benzyl-β-D-ribofuranosyl fluoride (1) with BF3*OEt2 in CH2Cl2 gave the intramolecular C-arylation product (2) formed from the reaction with the 2-O-benzyl group in a 83percent yield.Catalytic transfer hydrogenolysis of 2 using HCO

HIGHLY STEREOSELECTIVE C-α-D-RIBOFURANOSYLATION. REACTIONS OF D-RIBOFURANOSYL FLUORIDE DERIVATIVES WITH ENOL TRIMETHYLSILYL ETHERS AND ALLYLTRIMETHYLSILANE

2,3,5-Tri-O-methyl-D-ribofuranosyl fluoride (6), 2,3-di-O-benzyl-5-O-methyl-D-ribofuranosyl fluoride (7), and 5-O-benzyl-2,3-di-O-methyl-D-ribo-furanosyl fluoride (8) were obtained in 57 (6α, 15; and 6β, 42), 87 (7α, 22; and 7β, 65) and 85.5 (8α, 35.5; an