98830-92-3Relevant academic research and scientific papers
Synthesis of α-stannyl α,β-unsaturated carboxylic esters
Zapata, Antonio J.,Fortoul R., Corina,Acuna A., Carola
, p. 69 - 74 (2007/10/02)
A synthetic method for the preparation of α-stannyl α,β-unsaturated esters is described.The lithium enolate derived from tert-butyl α-(tri-n-butylstannyl)-α-(trimethylsilyl)acetate reacts with aldehydes to give moderate to good yields of α-stannylated products.The method is not applicable to enolizable ketones.
Reactions of t-butyl (trialkylstannyl)(trimethylgermyl)acetates and application of their anions to the Peterson-type reaction
Kanemoto, Naohide,Sato, Yoshiro,Inoue, Sumie
, p. 25 - 32 (2007/10/02)
Three t-butyl (trialkylstannyl)(trimethylgermyl)acetates were synthesized and subjected to the Peterson-type reaction with carbonyl compounds. t-Butyl 2-(trimethylgermyl)-2-alkenoates were obtained as the main products from (tri-n-butyl-stannyl)-2-alkenoates and 2-alkenoates as minor products.
Preparation of vinylstannanes via the Peterson reaction
Ager, David J.,Cooke, Glen E.,East, Michael B.,Mole, Susan J.,Rampersaud, Ashraff,Webb, Victoria J.
, p. 1906 - 1908 (2008/10/08)
The condensation of anions derived from (phenylthio)(tri-n-butylstannyl)(trimethylsilyl)methane (2a), tert-butyl (tri-n-butylstannyl)(trimethylsilyl)acetate (2b), and (tri-n-butylstannyl)(trimethylsilyl)methane (2c) with carbonyl compounds was used to com
