98830-99-0Relevant articles and documents
Synthesis of α-stannyl α,β-unsaturated carboxylic esters
Zapata, Antonio J.,Fortoul R., Corina,Acuna A., Carola
, p. 69 - 74 (1993)
A synthetic method for the preparation of α-stannyl α,β-unsaturated esters is described.The lithium enolate derived from tert-butyl α-(tri-n-butylstannyl)-α-(trimethylsilyl)acetate reacts with aldehydes to give moderate to good yields of α-stannylated products.The method is not applicable to enolizable ketones.