Journal of Organometallic Chemistry p. 69 - 74 (1993)
Update date:2022-08-02
Topics:
Zapata, Antonio J.
Fortoul R., Corina
Acuna A., Carola
A synthetic method for the preparation of α-stannyl α,β-unsaturated esters is described.The lithium enolate derived from tert-butyl α-(tri-n-butylstannyl)-α-(trimethylsilyl)acetate reacts with aldehydes to give moderate to good yields of α-stannylated products.The method is not applicable to enolizable ketones.
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