98877-62-4Relevant academic research and scientific papers
A Trialkylstannane-Mediated Approach to Acyloin Products
McGarvey, Glenn J.,Kimura, Masayuki
, p. 4655 - 4657 (1985)
α-Alkoxy organolithium compounds, generated through the treatment of the corresponding tri-n-butylstannane with n-BuLi, smoothly condense with N,N-dimethylamides to afford α-alkoxy carbonyl products.This condensation is functionally equivalent to a regiocontrolled acyloin condensation.
Stereochemical Consequences of Carbanion Asymmetry. An Access to 1,2-Diols
McGarvey, Glenn J.,Kimura, Masayuki
, p. 5420 - 5422 (2007/10/02)
The enantiofacial discrimination of some asymmetric α-alkoxy carbanions is described, as well as an illustration of their preparative utility.
