99007-02-0

Basic information

• Product Name: N'-(9-anthrylmethylene)-N-phenylcarbamohydrazonothioic acid
• Synonyms: N'-(9-anthrylmethylene)-N-phenylcarbamohydrazonothioic acid
• CAS NO: 99007-02-0
• Molecular Formula: C₂₂H₁₇N₃S
• Molecular Weight: 355.45548
• Mol File: 99007-02-0.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N'-(9-anthrylmethylene)-N-phenylcarbamohydrazonothioic acid(CAS DataBase Reference)
• NIST Chemistry Reference: N'-(9-anthrylmethylene)-N-phenylcarbamohydrazonothioic acid(99007-02-0)
• EPA Substance Registry System: N'-(9-anthrylmethylene)-N-phenylcarbamohydrazonothioic acid(99007-02-0)

Safety Data

• Hazardous Substances Data: 99007-02-0(Hazardous Substances Data)

Upstream product

• 5351-69-9 4-Phenyl-3-thiosemicarbazide 
• 642-31-9 9-anthracene aldehyde 
• 7512-18-7 anthracen-9-ylmethylene-hydrazone 
• 103-72-0 phenyl isothiocyanate 

Downstream Products

• 1228181-97-2 [(η6-p-cymene)RuCl(C14H9CHNNHC(S)NH(Ph))]Cl 

Relevant articles and documents

Aggregation-induced emission enhancement of anthracene-derived Schiff base compounds and their application as a sensor for bovine serum albumin and optical cell imaging

Three anthracene-based Schiff base complexes, R1–R3 (R1 = (E)-N′-((anthracen-10-yl)methylene)benzohydrazide; R2 = (E)-1-((anthracen-10-yl)methylene)-4-phenylsemicarbazide; and R3 = (E)-1-((anthracen-10-yl)methylene)-4-phenylthiosemicarbazide) were synthesized from 9-anthracenecarboxaldehyde, benzohydrazide, 4-phenylsemicarbazide and 4-phenylthiosemi-carbazide respectively, and characterized by various spectral techniques. The absorption spectral characteristics of R1–R3 were bathochromically tuned to the visible region by extending the π conjugation. These target compounds were weakly fluorescent in tetrahydrofuran (THF) solution because of rapid isomerization of the C=N double bond in the excited state. However, the aqueous dispersion of R1–R3 in the THF/water mixture by the gradual addition of water up to 90% resulted in an increase in the fluorescence intensity mainly due to aggregation-induced emission enhancement (AIEE) properties. The formation of nanoaggregates of R1–R3 were confirmed by scanning electron microscopy (SEM) and atomic force microscopy (AFM) techniques. The compounds R1–R3 are ideal probes for the fluorescence sensing of bovine serum albumin (BSA) and breast cancer cells by optical cell imaging.

Oxidative cyclization of thiosemicarbazide: a chemodosimetric approach for the highly selective fluorescence detection of cerium(iv)

A simple thiosemicarbazide-based chemodosimeter was employed to detect Ce4+ion through turn-on fluorescence. The sensing mechanism was based on oxidative cyclization. The chemodosimeter exhibited exceptional selectivity for Ce4+, which allowed the detection of as low as 11 nM Ce4+ion in an aqueous ethanol medium.

Compound with anti-tumor effect as well as preparation method and application thereof

The invention discloses a compound with an anti-tumor effect. The chemical name of the compound is monochloride-chlorine-(9-anthracene-N-phenyl thiosemicarbazide)-pentamethyl cyclopentadienyl rhodium (III); the structure formula of the compound is show