99027-35-7Relevant academic research and scientific papers
Dithioester-enabled chemodivergent synthesis of acids, amides and isothiazoles via C[sbnd]C bond cleavage and C[sbnd]O/C[sbnd]N/C[sbnd]S bond formations under metal- and catalyst-free conditions
Soni, Sonam,Koley, Suvajit,Singh, Maya Shankar
supporting information, p. 2512 - 2516 (2017/05/31)
An operationally simple and user-friendly process to access privileged scaffolds such as acids, amides and isothiazoles has been devised employing β-ketodithioesters for the first time. Remarkably, the new protocol involves combination of C[sbnd]C bond cl
THE REACTIONS OF ISOTHIAZOLIUM SALTS WITH NITROGEN NUCLEOPHILIC REAGENTS
Hassan, Mohamed E.,Magraby, M. A.,Aziz, Magda A.
, p. 1885 - 1892 (2007/10/02)
Isothiazolium salts were allowed to react with a number of nitrogen nucleophiles including ammonia, hydrazine, phenylhydrazine, hydroxylamine, and benzylamine.The products obtained suggest that the position of initial nucleophilic attack is at the sulphur
