99121-27-4Relevant academic research and scientific papers
1,3-Dithienium- and 1,3-Dithiolenium Salts, IV. 1,3-Dithian-2-ylium Tetrafluoroborates - New Agents for the Synthesis of 1-Deuterioaldehydes
Stahl, Ingfried
, p. 3166 - 3171 (2007/10/02)
The 1,3-dithian-2-ylium tetrafluoroborates 3 react in good yields with sodium borohydride (4) to give the 1,3-dithianes 6 and with sodium borodeuteride (5) to form the precursors 7 of 1-deuterated aldehydes 8.Three 1-deuterioaldehydes 8 are synthesized exemplarily by dethioacetalization of 7.
