19486-71-6Relevant articles and documents
Electrocatalytic Activation of Donor–Acceptor Cyclopropanes and Cyclobutanes: An Alternative C(sp3)?C(sp3) Cleavage Mode
Brandt, Felix,Jacob, Christoph R.,Jones, Peter G.,Kolb, Simon,Petzold, Martin,Werz, Daniel B.
, p. 15928 - 15934 (2021)
We describe the first electrochemical activation of D–A cyclopropanes and D–A cyclobutanes leading after C(sp3)?C(sp3) cleavage to the formation of highly reactive radical cations. This concept is utilized to formally insert molecula
Br?nsted Base-Catalyzed Tandem [2+4] Annulation/Tautomerization/Aromatization Reaction of α-Alkylidene Succinimides with 5-Alkenyl Thiazolones
Ge, Yanqing,Gong, Qi,Gu, Jing,Guo, Hongchao,Luo, Shan,Xie, Lei,Yang, Huimin,Yuan, Chunhao
, p. 3336 - 3347 (2021)
A Br?nsted base-catalyzed tandem [2+4] annulation/tautomerization/aromatization reaction of α-alkylidene succinimides with 5-alkenyl thiazolones has been developed for synthesis of functionalized thiazolo pyrones under mild conditions. The prepared thiazo
VISIBLE-LIGHT MEDIATED ORGANOPHOTOREDOX CATALYTIC DEUTERATION OF AROMATIC AND ALIPHATIC ALDEHYDES
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Paragraph 0052; 0056; 00103; 00111-00112, (2021/06/22)
Described are methods for preparing a deuterated aldehyde using with a photocatalyst and a hydrogen atom transfer agent in a H2O free solvent comprising D2O and an organic solvent under an inert gas. The methods may be used to convert a wide variety of aldehydes (e.g., aryl, alkyl, or alkenyl aldehydes) to C-1 deuterated aldehydes under mild reaction conditions.