99185-25-8

Basic information

• Product Name: 4-(2-nitro-phenyl)-acetoacetic acid
• Synonyms: 4-(2-nitro-phenyl)-acetoacetic acid
• CAS NO: 99185-25-8
• Molecular Weight: 223.185
• Mol File: 99185-25-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-(2-nitro-phenyl)-acetoacetic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(2-nitro-phenyl)-acetoacetic acid(99185-25-8)
• EPA Substance Registry System: 4-(2-nitro-phenyl)-acetoacetic acid(99185-25-8)

Safety Data

• Hazardous Substances Data: 99185-25-8(Hazardous Substances Data)

Upstream product

• 2033-24-1 cycl-isopropylidene malonate 
• 3740-52-1 2-(2-nitrophenyl)acetic acid 
• 66073-33-4 4-(2-nitrophenyl)-3-oxobutyric acid ethyl ester 
• 61417-33-2 ethyl 2-acetyl-3-oxo-4-(2-nitrophenyl)butanoate 

Downstream Products

• 1431726-78-1 (1R,5S,8R)-tert-butyl 7-hydroxy-2-(4-methylphenylsulfonyl)-8-(2-nitrophenyl)-2-azabicyclo[3.3.1]non-6-ene-6-carboxylate 
• 160983-67-5 tert-butyl 4-(2-nitrophenyl)-3-oxobutanoate 
• 32588-36-6 indolylacetic acid 

Relevant articles and documents

Organocatalyzed asymmetric synthesis of morphans

A general effective organocatalyzed synthesis of enantioenriched morphans with up to 92% ee was developed. The morphan scaffold was constructed in a one-pot tandem asymmetric organocatalyzed Michael addition followed by a domino Robinson annulation/aza-Michael intramolecular reaction sequence from easily available starting materials.